منابع مشابه
Conformations and Mutarotations of Poly(5-methyl-l-proline)
Optically active poly(cis-5-methyl-L-proline) and poly(trans-5-methyl-L-proline) were synthesized from their respective N-carboxy-anhydrides (NCA). Analysis of the i.r., u.v., n.m.r., ORD, and CD spectra of the polymers showed that two different conformations of each polymer exist in the solid and in solution in appropriate solvents. Form I and form II of poly(trans-5-methylL-proline) were foun...
متن کاملA non-planar peptide bond in L-seryl-L-valine.
The molecular structure of (I) is shown in Fig. 1. Bond lengths and angles are normal, but the unusual non-planarity of the peptide bond is quite evident. The associated torsion angle C1ÐC3ÐN2ÐC4 (!) is 157.37 (15) , a deviation from 180 that is superceded among small chiral peptides only by the 156.6 ! angle in N-(tert-butoxycarbonyl)-l-Pro-l-Leu benzyl ester (Sugino et al., 1978). Fig. 2(a) s...
متن کاملGas-Phase and Solution Conformations of the alpha-L-Iduronic Acid Structural Unit of Heparin
The IdoA2S structural unit of heparin (subunit G) may oscillate among the three conformations (4C1, 1C4, and 2So). Only the twisted boat conformation allowed the biologically active pentasaccharide unit of heparin (DEFGH) to bind to antithrombin. Our work reports, in detail, the results of systematic large-scale theoretical investigations of the three basic conformations (4C1, 1C4, and 2So) of ...
متن کاملRaman studies of solution polyglycine conformations.
Polyglycine (polygly) is an important model system for understanding the structural preferences of unfolded polypeptides in solution. We utilized UV resonance and visible Raman spectroscopy to investigate the conformational preferences of polygly peptides of different lengths in water containing LiCl and LiClO(4). Lithium salts increase the solubility of polygly. Our study indicates that in sol...
متن کاملNutritional Feasibility of L-Valine Inclusion in Commercial Broiler Diets
Introduction The poultry industry has recently dealt with fluctuating spikes in the price of various feed ingredients. When the cost of protein-rich feed ingredients goes up, the reduction of dietary crude protein via the use of commercially available amino acids becomes an effective formulation strategy that can reduce diet costs, maintain broiler performance and not interfere with feed millin...
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ژورنال
عنوان ژورنال: Biopolymers
سال: 1969
ISSN: 0006-3525,1097-0282
DOI: 10.1002/bip.1969.360070114